The authors dissolved 10 mg rr-P3HT in 1 mL chloroform, dispensed 0.3 mL per sample, and spin-deposited the films at 600 rpm for 30 s on 20 × 20 mm glass substrates. Film thickness was calibrated to about 65 nm, and samples were then annealed at 80 °C for 20–100 min to study structural ordering.